Everything about Glass-ceramic totally explained
Glass-ceramic materials share many properties with both
glass and more traditional crystalline
ceramics. It is formed as a glass, and then made to
crystalize partly by
heat treatment. Unlike
sintered ceramics, glass-ceramics have no pores between crystals.
While materials such as
"vaseline" glass are also glass-ceramics, the term mainly refers to a mix of
lithium-,
silicon-, and
aluminium-
oxides which yields an array of materials with interesting thermomechanical properties. The most commercially important of these have the distinction of being impervious to
thermal shock. Originally developed for use in the
mirrors and mirror mounts of astronomical
telescopes, these materials have become known and entered the domestic market through its use in glass-ceramic
cooktops, as well as
cookware and bakeware.
The crystalline component of thermal glass-ceramics, beta
spodumene, has a
negative coefficient of thermal expansion, which contrasts with the positive coefficient of the glass. Adjusting the proportion of these two materials offers a wide range of possible coefficients in the finished composite.
When an interface between materials will be subject to thermal
fatigue, glass-ceramics can be adjusted to match the coefficient of the material that'll be bonded to. At a certain point, generally between 70% and 78% crystallinity, the two coefficients balance such that the glass-ceramic as a whole has a thermal expansion coefficient that's very close to zero.
Glass-ceramic is a mechanically very strong material and can sustain repeated and quick temperature changes up to 800–1000
°C. At the same time, it has a very low
heat conduction coefficient and can be made nearly transparent (15–20% loss in a typical cooktop) for radiation in the
infrared wavelengths.
Today, there are two major types of electrical
stoves with cooktops made of glass-ceramic:
- A glass-ceramic stove uses electrical heating coils or infrared halogen lamps as the heating elements. The surface of the glass-ceramic cooktop above the burner heats up, but the adjacent surface remains cool because of the low heat conduction coefficient of the material.
- An induction stove heats a metal pot's bottom directly through electromagnetic induction.
Some well-known brands of glass-ceramics are
Ceran
(cooktops),
Eurokera
(cooktop, stoves and fireplaces),
Zerodur (telescope mirrors), or
Macor.
German manufacturer
Schott has introduced Zerodur in
1968, Ceran followed in
1971.
Nippon Electric Glass of Japan
are another worldwide manufacturer of glass ceramics, whose related products in this area include Firelite and Neoceram fire rated glass.
The same class of material is also used in
Corningware dishes, which can be taken from the freezer directly to the oven with no risk of thermal shock.
Care and cleaning
Glass-ceramic cooktops can be scratched very easily, so care must be taken not to slide the cooking pans over the surface. Food with a high sugar content (such as jam) should never be allowed to dry on the surface if it spills, otherwise damage will occur. Cleaning is best carried out by using a soft cloth along with a special glass-ceramic cleaner that applies a thin protective film on the glass.
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